stretching vibration वाक्य
उदाहरण वाक्य
मोबाइल
- M " OH stretching vibrations occur below about 600 cm " 1.
- The symmetric and asymmetric stretching vibrations are close to each other, so the rotational fine structures of these bands overlap.
- The infrared spectrum of liquid water is dominated by the intense absorption due to the fundamental O-H stretching vibrations.
- U O stretching vibrations at ca . 880 cm " 1 ( Raman spectrum ) and 950 cm " 1 ( infrared spectrum ).
- It has an O-H stretching vibration at 3092.1 cm " 1, which compares to 3125.3 cm " 1 in ice.
- IR absorption of the CN stretching vibration of [ Fe ( btr ) 2 ( NCS ) 2 ] H 2 O at different temperatures in the cooling mode ( a ) and heating mode ( b ).
- In the spectrum of CH 5 + three asymmetric stretching vibrations are present around 2800 3000 cm " 1, a rocking vibration at 1300 cm " 1, and a bending vibration at 1100 1300 cm " 1.
- At the temperature of liquid helium, 4K, the vibronic structure was completely resolved, with zero intensity for the purely electronic transition, and three side-lines corresponding to the asymmetric U-Cl stretching vibration and two asymmetric Cl-U-Cl bending modes.
- This adapted figure shows the fraction of the HS centers, ( x ), as a function of temperature as calculated from the absorption of the CN stretching vibrations of [ Fe ( btr ) 2 ( NCS ) 2 ] " H 2 O . This plot shows a relatively large hysteresis.
- For an S N 1 reaction, since the carbon is converted into an sp 2 hybridized carbenium ion during the transition state for the rate-determining step with an increase in C ?-H ( D ) bond order, an inverse kinetic isotope effect would be expected if only the stretching vibrations were important.
- If the zero-point energy difference between the stretching vibrations of a carbon-hydrogen and carbon-deuterium bond is allowed to disappear in the transition state, the expression given above predicts a maximum for k H / k D as 6.9 . If the weakening of two bending vibrations are also taken into account, k H / k D values as large as 15-20 can be predicted.
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